Molecular spectroscopy 1: rotational and vibrational spectra Quantum theory: techniques and applications Quantum theory: introduction and principles Physical transformations of pure substances Physical Chemistry by Peter Atkins & Julio De Paula Table of Contents Fundamentals

To make the material more readily accessible within the context of courses, descriptions of polymerization, photochemistry, and enzyme- and surface-catalyzed reactions are now part of Chapters 21 (The rates of chemical reactions) and 22 (Reaction dynamics)-already familiar to readers of the text-and a new chapter, Chapter 23, on Catalysis. Part 3 has lost chapters dedicated to the kinetics of complex reactions and surface processes, but not the material, which we regard as highly important in a contemporary context. We have also paid more attention to computational chemistry, and have revised the coverage of this topic in Chapter 10. In Part 2 (Structure) the chapters have been updated with a discussion of contemporary techniques of materials science-including nanoscience-and spectroscopy. New Impact sections highlight the application of principles of thermodynamics to materials science, an area of growing interest to chemists. For example, the material on phase diagrams no longer has its own chapter but is now distributed between Chapters 4 (Physical transformation of pure substances) and 5 (Simple mixtures). We continue to respond to the cautious shift in emphasis away from classical thermodynamics by combining several chapters in Part 1 (Equilibrium), bearing in mind that some of the material will already have been covered in earlier courses. The text is still divided into three parts, but the material has been moved between chapters and the chapters themselves have been reorganized. However, it should always be borne in mind that much of the bulk arises from the numerous pedagogical features that we include (such as Worked examples, Checklists of key equations, and the Resource section), not necessarily from the density of information. Our goal is to keep the book flexible to use, accessible to students, broad in scope, and authoritative, without adding bulk. We have followed our usual tradition in that this new edition of the text is yet another thorough update of the content and its presentation.

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